Complete the table to show what would happen to the position of the following gas phase equilibria changes were made. Tick the correct column in each case.
Equilibrium
2 A(g) + B(g) ⇌ X(g) + Z(g)
A(g) + B(g) ⇌ X(g) + Z(g)
B(g) ⇌ X(g) + Z(g) + Y(g)
X(g) + Y(g) ⇌ 2 B(g)
2 X(g) ⇌ 2 A(g) + B(g)
2) Sulfur trioxide is made by the following reaction. The forward reaction is exothermic.
dynamic equilibrium in a closed system.
a) i) What is a closed system?
ii) What are the features of a system in a state of dynamic equilibrium?
1
2
3
4
b) i) If the temperature of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
ii) Explain your reasoning.
c) i) If the pressure of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
ii) Explain your reasoning.
d) i) If more oxygen was added to the mixture, what would happen to the yield of sulfur trioxide?
26-Jun-2015
Complete the table to show what would happen to the position of the following gas phase equilibria
changes were made. Tick the correct column in each case.
∆H
Increase temperature Increase pressure
moves
left
no
move
move
right
moves
left
no
move
move
right
exothermic
endothermic
exothermic
exothermic
endothermic
trioxide is made by the following reaction. The forward reaction is exothermic. This reaction reaches a state of
dynamic equilibrium in a closed system.
2 SO2
(g) + O2(g) ⇌ 2 SO3(g)
What is a closed system?
What are the features of a system in a state of dynamic equilibrium?
2
4
If the temperature of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
Explain your reasoning.
e of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
Explain your reasoning.
If more oxygen was added to the mixture, what would happen to the yield of sulfur trioxide?
LE CHATELIER’S PRINCIPLE 2
Chemsheets AS 1039
Complete the table to show what would happen to the position of the following gas phase equilibria if the following
Increase pressure Remove some of B
move
right
moves
left
no
move
move
right
This reaction reaches a state of
What is a closed system? .
.***
2 .**
.**
4 .***
If the temperature of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
.
Explain your reasoning. .
.
.
e of this equilibrium was increased, what would happen to the yield of sulfur trioxide?
.
Explain your reasoning. .
.
.
If more oxygen was added to the mixture, what would happen to the yield of sulfur trioxide?
.
LE CHATELIER’S PRINCIPLE 2
© www.CHEMSHEETS.co.uk 26-Jun-2015 Chemsheets AS 1039
ii) Explain your reasoning. ..
..
.***.
3) When bismuth chloride is added to water, a reaction occurs and a white precipitate forms. The following equilibrium is
set up. What would be the effect on the amount of precipitate if sodium hydroxide solution is added to the mixture
(explain your answer)?
BiCl3
(aq) + H2O(l) ⇌ BiOCl(s) + 2 HCl(aq)
112л хг 67,2г хг
СО2--- С х=60 n(C)=60/12=5моль Н2О Н2 х=7,47г
22,4л 12г 18г 2г
n(H)=7.47моль
Х :У= 5 :7.47= 1:1,5
С1Н1,5= 12+1.5= 13.5 27/13.5=2 С2Н3*2=M(С4Н6)=12*4+6=54г/моль ответ бутин или бутадиен С4Н6
CsI
Ar(Cs)=133g/mol
Ar(I) = 127g/mol
Mr(CsI)=260g/mol
W(Cs)= 133/260*100=51.2%
W(I)=127/260*100=48.8%
H2S
Ar(H)=1g/mol
Ar(S)=32g/mol
Mr(H2S)=34g/mol
W(H)=2*1/34*100=6%g/mol
W(S)=32/34*100=94%
C3N4
Ar(C)=12g/mol
Ar(N)=14g/mol
Mr(C3N4)=92g/mol
W(C) = 3*12/92*100=39%
W(N)=4*14/92*100=61%
K2Cr2O7
Ar(K)=39g/mol
Ar(Cr)=52g/mol
Ar(O)=16g/mol
Mr(K2Cr2O7)=294g/mol
W(K)=2*39/294*100=26.5%
W(Cr)=2*52/294*100=35.4%
W(O) =7*16/294*100=38.1%
NH4NO3
Ar(N)=14g/mol
Ar(H)=1g/mol
Ar(O)=16g/mol
Mr(NH4NO3)=80g/mol
W(N)=2*14/80*100=35%
W(H)=4*1/80*100=5%
W(O)=3*16/80*100=60%