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Даны кристаллические вещества:
Na2SO4, Na2CO3, NaCl.
Добавив воды получим растворы.
Определить сульфат-ион в сульфате натрия можно, добавив, к примеру, хлорид бария.
Молекулярное уравнение реакции:
Na2SO4 + BaCl2 -> BaSO4⬇️ + 2NaCl
ПИ:
2Na(+)+SO4(2-) + Ba(2+)+2Cl(-) -> BaSO4⬇️ + 2Na(+)+2Cl(-)
СИ:
SO4(2-) + Ba(2+) -> BaSO4⬇️
Сульфат бария выпадает в белый осадок.
Карбонат-ион обнаруживается добавлением кислоты, например, соляной.
Молекулярное уравнение реакции:
Na2CO3 + 2HCI -> 2NaCl + H2O + CO2⬆️
ПИ:
2Na(+)+CO3(2-) + 2H(+)+2CI(-) -> 2Na(+)+2Cl(-) + H2O + CO2⬆️
СИ:
CO3(2-) + 2H(+) -> H2O + CO2⬆️
Происходит образование пузырьков углекислого газа.
Обнаружить хлорид-ион возможно в результате реакции с нитратом серебра.
Молекулярное уравнение реакции:
NaCl + AgNO3 -> NaNO3 + AgCl⬇️
ПИ:
Na(+)+Cl(-) + Ag(+)+NO3(-) -> Na(+)+NO3(-) + AgCl⬇️
СИ:
CI(-) + Ag(+) -> AgCl⬇️
Хлорид серебра выпадает в белый творожистый осадок.
Найдем массу и количество уксусной кислоты:
m(CH3COOH) = m(р-ра)*w = 60 * 0,09 = 5,4 г
n(CH3COOH) = m(CH3COOH)/M(CH3COOH) = 5,4/60 = 0,09 моль
Найдем массу и количество гидроксида натрия:
m(NaOH) = m(р-ра)*w=40*0,08= 3,2 г
n(NaOH) = m(NaOH)/M(NaOH) = 3,2/40 = 0,08 моль
След-но: уксусная к-та в избытке, расчет ведем по гидроксиду натрия.
n(NaOH) = n(CH3COONa) = 0,08 моль
m(CH3COONa) = n(CH3COONa)*M(CH3COONa) = 0,08*82 = 6,56г
ответ: 6,56г.