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m(FeS+ZnS)=28,2 г
m(CuCl₂) = 405 г
ω(CuCl₂) = 10%= 0.1
ω(FeS) - ?
ω(ZnS) - ?
Решение.
Определим объем газа, который выделился:
m(CuCl₂) = 405 г*0,1=40,5 г
135 г 22,4 л
CuCl₂ + H₂S = CuS↓ + 2HCl↑
40,5 г х л
х=V(H₂S) = 6,72 л
Примем массу FeS за х г, а объем вы₂делившегося H₂S за у л, тогда масса ZnS = (28.2-х) г, а объем выделившегося H₂S = (6,72-у) л
88 г 22,4 л
FeS + 2HCl = FeCl₂ + H₂S↑
х г у л
97 г 22,4 л
ZnS + 2HCl = ZnCl₂ + H₂S↑
28,2-х 6,72-у
Составляем систему двух уравнений:
22,4х = 88у
22,4*(28,2-х) = 97*(6,72-у)
Решив систему уравнений, найдем х
х=m(FeS)=8,8 г
m(ZnS)=28.2 г - 8,8 г = 19,4 г
ω(FeS) = 8,8/28,2=0,3121 = 31,21%
ω(ZnS) = 19.4/28,2=0,6879 = 68,79%
по таблице растворимости узнать идет или не идет реакция не возможно, но можно узнать идет ли реакция до конца (к примеру если образуется вода или осадок, который в таблице растворимости обозначен Н (нерастворимый), а также газ (ну это уже по свойствам веществ).
а возможность протекания реакции определяется по свойствам веществ.
Ca(OH)2+CO2=CaCO3 + H2O возможна (основание реагирует с кислотным оксидом)и идет до конца ( образовалась вода и осадок)
Ca(OH)2+ 2HNO3= Ca(NO3)2+ 2H2O, возможна (основание + кислота) и идетдо конца , т.к. образовалась вода
Ca(OH)2 + KOH не возможна (сильное основание с щелочью не взаимодействуют)
Ca(OH)2 + Fe2O3 не возможна (сильное основание и оксид основный не взаимодействуют)
3Ca(OH)2 + Al2(SO4)3 = 3CaSO4 + 2Al(OH)3 возможна (Al(OH)3 нерастворим , выпадает в осадок)