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Дано: m(Na2SO3) = 126 г, ω(Na2SO3) = 10%, m(HCl) = 73 г, ω(HCl) = 10%. Решение: 1) составим уравнение реакции: Na2SO3 + 2HCl = 2NaCl + H2О + SO2↑ из уравнения видно, что количество вещества n(Na2SO3) отностся к n(SO2), как 1:1 (по коэффициентам), 2) по формуле n=m/M рассчитываем количество вещества сульфита натрия, но для этого найдем массу его вещества, т.к. нам дана в условии лишь масса его раствора: m(вещ-ва) Na2SO3 = (m (р-ра)*ω) /100%, m(вещ-ва) Na2SO3 = (126 г *10%)/100% = 12,6 г. 3) рассчитаем молярную массу вещества: M (Na2SO3) = 23*2 + 32 + 16 *3 = 126 г/моль, 4) найдем количество вещества: n (Na2SO3) = 12,6 г/ 126 г/моль = 0,1 моль, 5) n(SO2) = n(Na2SO3) = 0,1 моль, 6) из формулы n = V/ Vm найдем объем сернистого газа, учитывая, что Vm = 22,4 л/моль. получим: V (SO2) = n * Vm = 0,1 моль * 22,4 л/моль = 2,24 л. ответ: объем сернистого газа равен 2,24 л. Удачи;)
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m(Na2SO3) = 126 г,
ω(Na2SO3) = 10%,
m(HCl) = 73 г,
ω(HCl) = 10%.
Решение:
1) составим уравнение реакции:
Na2SO3 + 2HCl = 2NaCl + H2О + SO2↑
из уравнения видно, что количество вещества n(Na2SO3) отностся к
n(SO2), как 1:1 (по коэффициентам),
2) по формуле n=m/M рассчитываем количество вещества сульфита натрия, но для этого найдем массу его вещества, т.к. нам дана в условии лишь масса его раствора:
m(вещ-ва) Na2SO3 = (m (р-ра)*ω) /100%,
m(вещ-ва) Na2SO3 = (126 г *10%)/100% = 12,6 г.
3) рассчитаем молярную массу вещества: M (Na2SO3) = 23*2 + 32 + 16 *3 = 126 г/моль,
4) найдем количество вещества:
n (Na2SO3) = 12,6 г/ 126 г/моль = 0,1 моль,
5) n(SO2) = n(Na2SO3) = 0,1 моль,
6) из формулы n = V/ Vm найдем объем сернистого газа, учитывая, что Vm = 22,4 л/моль.
получим: V (SO2) = n * Vm = 0,1 моль * 22,4 л/моль = 2,24 л.
ответ: объем сернистого газа равен 2,24 л.
Удачи;)