Если бы обр-ь только 1 соль - KHCO3, т.е. весь KOH кол-м в-ва (1.13*106.2*0.14)/56 = 0.3 моль вст-л в р-ию с 0.3 моль CO2: KOH + CO2 = KHCO3, то м.д. соли была бы равна 100*0.3/(1.13*106.2+44*0.3) = 0.2252 или 22.52%;
значит с CO2 прот-и 2 послед-х р-ии:
1) KOH + CO2 = KHCO3 и
2) KHCO3 + KOH = K2CO3 + H2O;
пусть x моль CO2 вст-о в р-ию 1) с x моль KOH и обр-ь x моль KHCO3, а KOH ост-я в кол-е 0.3-x моль;
в р-ию 2) вст-т KOH и KHCO3 в кол-е по 0.3-x моль и обр-я по 0.3-x моль K2CO3 и H2O, а KHCO3 ост-я в кол-е x-(0.3-x) = 2*x-0.3 моль;
масса р-ра KOH увел-я на 44*x г CO2;
по условию, 100*(2*x-0.3)/(1.13*106.2+44*x) = 0.074, откуда x = 0.1976 моль;
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значит с CO2 прот-и 2 послед-х р-ии:
1) KOH + CO2 = KHCO3 и
2) KHCO3 + KOH = K2CO3 + H2O;
пусть x моль CO2 вст-о в р-ию 1) с x моль KOH и обр-ь x моль KHCO3, а KOH ост-я в кол-е 0.3-x моль;
в р-ию 2) вст-т KOH и KHCO3 в кол-е по 0.3-x моль и обр-я по 0.3-x моль K2CO3 и H2O, а KHCO3 ост-я в кол-е x-(0.3-x) = 2*x-0.3 моль;
масса р-ра KOH увел-я на 44*x г CO2;
по условию, 100*(2*x-0.3)/(1.13*106.2+44*x) = 0.074, откуда x = 0.1976 моль;
2(CH3)2NH + 7.5O2 = 4CO2 + N2 + 7H2O;
n (CH3)2NH = n CO2/2 = 0.0988 моль;
V (CH3)2NH = 22.4*0.0988 = 2.21312 = 2.2 л.
не знаю что писать но спс за Hit the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are notified that any dissemination distribution or copying of this email and any attachments is intended only for the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you are not the intended recipient you.
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